CJHFY - CADOX M-50 A

Product Identification

Product ID:CADOX M-50 A
MSDS Date:02/25/1998
FSC:6810
NIIN:01-120-0408
Status Code:A
MSDS Number: CJHFY

Responsible Party
AKZO NOBEL CHEMICALS INC
300 S. RIVERSIDE PLAZA
CHICAGO, IL 60606
US

Emergency Phone: 800-828-7929

Info Phone: 800-828-7929

Cage: 97854

Contractor
MAHOGANY CO.
MAYS LANDING, NJ 08330-2006 US

Telephone: 609-625-8101

Cage: 5U815

Ingredients

METHYL ETHYL KETONE PEROXIDE (MEKP) (CERCLA)

CAS: 1338-23-4

RTECS: EL9450000

OSHA PEL C 0.7 PPM

ACGIH TLV: C 0.2 PPM; 9596

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS


HYDROGEN PEROXIDE (SARA 302)

CAS: 7722-84-1

RTECS: MX0900000

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM; 9596


1,3-PENTANEDIOL,2,2,4-TRIMETHYL-,DIISOBUTYRATE

CAS: 6846-50-0

RTECS: SA1420000


WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL NOT RELEVANT

ACGIH TLV: NOT RELEVANT

Hazards

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS > 3,200 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GI TRACTS. SKIN CONTACT CAN CAUSE CHEMICAL BURNS WITH SEVERE
BLISTERING. EYE CONTACT CAN CAUSE SEVERE REACTION & MAY RESULT IN
LOSS OF FUNCTIONAL VISION IN THE INVOLVED EYE. INHALATION OF
VAPOR, MIST OR AEROSOL IS EXPECTED TO BE SEVERELY IRRITATING TO THE
RESPIRATORY TRACT. INGESTION CAN CAUSE SEVERE IRRITATION OR BURNS
OF THE MOUTH, THROAT, ESOPHAGUS AND ST OMACH.
Explanation of Carcinogenicity:NONE GIVEN BY MANUFACTURER.
Effects of Overexposure:INHALED-SEVERE IRRITATION OF UPPER RESPIRATORY
TRACT. SKIN-CHEMICAL BURNS WITH SEVERE BLISTERING. EYES-SEVERE
REACTION, POSSIBLE LOSS OF FUNCTIONAL VISION. INGESTED-SEVERE
IRRITATION OR BURNS OF MOUT H, THROAT, ESOPHAGUS, STOMACH.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
AND/OR RESPIRATORY DISEASE MAY BE AT INCREASED RISK IF EXPOSED TO
THIS MATERIAL.

First Aid

First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN IF NEEDED.
EYES:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS
OPEN. CALL PHYSIC IAN. SKIN:IMMEDIATELY WASH WITH SOAP & PLENTY OF
WATER.INGESTED:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK PLENTY
OF WATER. SEEK IMMEDIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONS CIOUS OR CONVULSING PERSON.

Fire Fighting

Flash Point Method:SCC
Flash Point:=82.C, 179.6F
Extinguishing Media:USE WATER FOG, DRY CHEMICAL, CARBON DIOXIDE, OR
FOAM EXTINGUISHING AGENTS. EXTINGUISH LARGE FIRES WITH LARGE
AMOUNTS OF WATER SPRAY, FOG OR FOAM FROM A SAFE/PROTECTED POSITION.
Fire Fighting Procedures:EVACUATE NON-ESSENTIAL PERSONNEL. FIRE
FIGHTERS SHOULD WEAR FULL-FACE, SELF-CONTAINED BREATHING APPARATUS
AND IMPERVIOUS CLOTHING. COOL FIRE EXPOSED CONTAINERS WITH WATER TO
PREVENT RUPTURE. HIGH PRES SURE WATER MAY SPREAD PRODUCT. DIKE FIRE
WATER FOR LATER DISPOSAL. DO NOT ALLOW CONTAMINATED WATER INTO
WATERWAYS.
Unusual Fire/Explosion Hazard:THIS PRODUCT CAN PRODUCE FLAMMABLE VAPORS
WHICH MAY TRAVEL TO ASOURCE OF IGNITION & FLASH BACK. PEROXIDES AND
PEROXIDE DECOMPOSITION PRODUCTS ARE FLAMMABLE & CAN IGNITE WITH
EXPLOSIVE FORCE IF CONFINE D.

Accidental Release

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. CONTAIN SPILL. SOAK UP SPILL WITH
NON-FLAMMABLE ABSORBANT. SWEEP UP ABSORBED MATERIAL AND PLACE IN A
CHEMICAL WASTE CONTAINER FOR DISPOSAL. PREVENT FROM ENTERING
SEWERS.
Neutralizing Agent:NOT RELEVANT

Handling

Handling and Storage Precautions:WEAR PROTECTIVE CLOTHING WHEN HANDLING
TO AVOID SKIN & EYE CONTACT. STORAGE TEMPERATURES SHOULD NOT EXCEED
MAXIMUM STORAGE TEMPERATURES OF 86F/30C. TO PREVENT
SELF-ACCELERATING DECOMPOSITION, STORAGE FACILITY TEMPERATURES
SHOULD NEVER EXCEED 131F/55C. KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED. STORE AWAY FROM
AMINES, ACIDS, ALKALIS AND HEAVY METAL COMPOUNDS (EG DRIERS, METAL
SOPAS AND ACCELERATORS). CONTAINERS SHOULD NOT BE OPENED UNTIL
READY FOR USE. USE CLE AN, NON-SPARKING TOOLS & EQUIPMENT WHEN
HANDLING.

Exposure Controls

Respiratory Protection:USE A NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR
WITH DUST, MIST, & FUME FILTERS TO REDUCE POTENTIAL FOR INHALATION
EXPOSURE AND ADEQUATE VENTILATION IS NOT AVAILABLE. CHANGE FILTERS
AFTER EACH USE/SHIFT . WHERE EXPOSURE POTENTIAL REQUIRES A HIGHER
LEVEL OF PROTECTION, USE A NIOSH-APPROVED PRESSURE DEMAND AIR
SUPPLIED RESPIRATOR.
Ventilation:USE APPROPRIATE VENTILATION MEASURES (LOCAL EXHAUST,
ENCLOSED SYSTEM, PROCESS ISOLATION, ETC) THAT WILL MAINTAIN
EXPOSURES BELOW TLV(S).
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:CHEMICAL GOGGLES AND/OR FULL FACE SHIELD.
Other Protective Equipment:SAFETY SHOWERS, EYE WASH FOUNTAINS OR OTHER
MEANS TO GENTLY FLUSH EYES WITH TEPID WATER SHOULD BE READILY
AVAILABLE. USE IMPERMEABLE CLOTHING AND FOOTWEAR.
Work Hygienic Practices:UNPROTECTED SKIN EXPOSED TO VAPOR, AEROSOL, OR
MIST MUST BE THOROUGHLY WASHED BEFORE EATING, DRINKING, SMOKING AND
AT THE END OF THE WORKSHIFT.
Supplemental Safety and Health
ELECTRICALLY GROUNDED TANKS AND CONTAINERS SHOULD ALWAYS BE USED AS
SHOULD NON-SPARKING, ELECTRICALLY GROUNDED HAND TOOLS AND
APPLIANCES. GROUND OR BOND TO GROUND ALL VESSELS WHEN TRANSFERRING
TO PREV ENT ACCUMULATION OF STATIC ELECTRICITY. EMPTY CONTAINER MAY
RETAIN PRODUCT RESIDUES. FOLLOW ALL WARNINGS & PRECAUTIONS.

Chemical Properties

HCC:P1
Boiling Pt:B.P. Text:N/D
Melt/Freeze Pt:M.P/F.P Text:N/D
Vapor Pres:N/D
Vapor Density:N/D
Spec Gravity:1.0 @ 20 DEG C
pH:N/D
Evaporation Rate & Reference:N/D
Solubility in Water:N/D
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH A FAINT KETONE ODOR

Stability

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ACIDS, STRONG ALKALIS, STRONG OXIDIZERS,
ACCELERATORS AND REDUCING AGENTS.
Stability Condition to Avoid:THIS PRODUCT IS STABLE AT TEMPERATURES UP
TO 131F (55 C).
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS INCLUDE CARBON
DIOXIDE, CARBON MONOXIDE, ETHANE AND METHANE.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION IS NOT
EXPECTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES.

Disposal

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
REUSING, RECYCLING OR INCINERATION IS RECOMMENDED. EPA HAZARDOUS
WASTE NUMBERS: U160, D003, D0 02

Toxicology

Toxicological Information:INHALATION TOXICITY DATA IS NOT AVAILABLE FOR
THIS PRODUCT. HOWEVER, THE ACUTE LC50 FOR A SIMILAR PRODUCT IS 17
MG/L IN RATS (4 HR EXPOSURE). INHALATION CHRONIC EXPOSURE:
PROLONGED/REPEATED INHALATION IS EXPECTED TO BE SEVERELY
IRRITATINGTO THE RESPIRATORY SYSTEM. DERMAL TOXICITY DATA IS NOT
AVAILABLE FOR THIS PRODUCT. HOWEVER, THE DERMAL LD50 FOR A SIMILAR
PRODUCT IS 4000 MG/KG IN RABBITS. EYE T OXICITY-THIS PRODUCT IS
EXPECTED TO BE CORROSIVE TO THE EYES BASED ON TESTS OF SIMILAR
PRODUCTS. INGESTION TOXICITY-DATA NOT AVAILABLE FOR THIS PRODUCT;
ACUTE LD50 (RAT) FOR SIMILAR PRODUCT IS 1017 MG /KG.

Other Information

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecology

Ecological:ECOTOXICOLOGICAL INFORMATION- THE ECOLOGICAL TOXICITYOF THIS
PRODUCT IS NOT KNOWN. DISTRIBUTION: OTHER ECOLOGICAL INFORMATION ON
THIS PRODUCT IS NOT KNOWN. CHEMICAL FATE: THIS PRODUCT IS EXPECTED
TO B E READILY BIODEGRADABLE.

Transport

Transport Information:SHIPPING DESCRIPTION: ORGANIC PEROXIDE TYPE E,
LIQUID (METHYL ETHYL KETONE PEROXIDE, <=40%) 5.2, UN3107, PGII.
REQUIRED LABELS: ORGANIC PEROXIDE ENVIRONMENTAL HAZARDOUS
SUBSTANCE: THIS PRODUCT CONTAIN S METHYL ETHYL KETONE PEROXIDE
WHICH IS AN ENVIRONMENTALLY HAZARDOUS MATERIAL PER 49 CFR 172.101
APPENDIX WITH A REPORTABLE QUANTITY OF 28.57 LBS.

Regulatory

SARA Title III Information:NONE SPECIFIED BY MANUFACTURER.
Federal Regulatory Information:METHYL ETHYL KETONE IS SUBJECT TO OR
LISED BY THE FOLLOWING: CERCLA HAZARDOUS SUBSTANCES, TSCA. HYDROGEN
PEROXIDE IS SUBJECT TO OR LISTED BY THE FOLLOWING:SARA 302, TSCA.
2,2,4-TRIETHYLPENTANEDIOL-1,3 -DIISOBUTYRATE IS SUBJECT TO OR
LISTED BY TSCA. WATER IS SUBJECT TO OR LISTED BY: TSCA.
State Regulatory Information:METHYL ETHYL KETONE IS SUBJECT TO OR LISED
BY THE FOLLOWING: MASSACHUSETTS SUBSTANCE LIST, NEW JERSEY R-T-K,
PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. HYDROGEN PEROXIDE IS SUBJECT
TO OR LISTED BY THE FOL LOWING:MASSACHUSETTS SUBSTANCE LIST, NEW
JERSEY R-T-K, PENNSYLVANIAS HAZARDOUS SUBSTANCE LIST.